The primary risk associated with "free chlorides" in Magnesium Oxide (MgO) boards is accelerated corrosion of metal building components and significant moisture damage to the structure
This risk is almost exclusively tied to older formulations of MgO boards that use magnesium chloride (MgCl2) as the binding agent (known as magnesium oxychloride cement).
Key Risks of Free Chlorides
- Severe Metal Corrosion
- The Problem: The MgCl2 salt is highly hygroscopic (it readily absorbs moisture from the air. In humid conditions, the salt absorbs enough water to form a liquid solution, a phenomenon known as "sweating" or "weeping.
- The Result: The liquid that leaks from the board's surface is a concentrated, salty brine rich in chloride ions. Chloride ions are extremely corrosive and can rapidly break down the protective oxide layers on metal.
- Corroded Components: This leads to the accelerated rusting and deterioration of metal fasteners (screws, nails), steel studs, and any adjacent metal components in the wall assembly, compromising the structural integrity of the building over time.
- Moisture-Related Damage and Degradation
- The Problem: The weeping liquid can saturate adjacent building materials.
- The Result: This can lead to:
- Degradation of Boards: The boards themselves may crack, swell, or lose cohesive strength.
- Moisture Uptake in Wood: Adjacent wooden elements may absorb the moisture, increasing the risk of mold, mildew, and rot.
- Staining and Efflorescence: Visible white salt deposits (efflorescence) or liquid stains appear on the board's surface
How Modern Boards Avoid This Risk
Modern, high-quality MgO boards, often called MgSO4 boards (Magnesium Sulfate boards), eliminate this risk by replacing the hygroscopic MgCl2 binder with magnesium sulfate MgSO4.
Since magnesium sulfate is significantly less hygroscopic and does not contain corrosive chloride ions, these new formulations prevent the "sweating" phenomenon and are non-corrosive to metal frames and fasteners.
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